Bulgakova, Svetlana A. and Volgutova, Evgeniya S. and Khokhlova, Irina E. (2012) Iron(III)-Mediated AGET ATRP of Methyl Methacrylate in the Absence of Additional Ligand. Open Journal of Polymer Chemistry, 02 (03). pp. 99-104. ISSN 2165-6681
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Abstract
The atom transfer radical polymerization on the mechanism of activator generation by electron transfer (AGET ATRP) of methyl methacrylate (MMA) in N,N-dimethylformamide (DMF) in the presence of the catalytic systems, namely, CCl4-FeCl3-1-acetyl-2-phenylhydrazine (APH) and CCl4-FeCl3-ascorbic acid (AA) is reported. The living feature of this process was confirmed by obtaining well-defined polymers with controlled molecular weight, narrow molecular weight distribution, and a chain-extension experiment. Both reducing agents, an APH as well as an AA, possess the equal kinetic activitis.
Item Type: | Article |
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Subjects: | East India Archive > Chemical Science |
Depositing User: | Unnamed user with email support@eastindiaarchive.com |
Date Deposited: | 23 Jun 2023 06:49 |
Last Modified: | 23 Oct 2024 03:53 |
URI: | http://ebooks.keeplibrary.com/id/eprint/1518 |