Iron(III)-Mediated AGET ATRP of Methyl Methacrylate in the Absence of Additional Ligand

Bulgakova, Svetlana A. and Volgutova, Evgeniya S. and Khokhlova, Irina E. (2012) Iron(III)-Mediated AGET ATRP of Methyl Methacrylate in the Absence of Additional Ligand. Open Journal of Polymer Chemistry, 02 (03). pp. 99-104. ISSN 2165-6681

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Abstract

The atom transfer radical polymerization on the mechanism of activator generation by electron transfer (AGET ATRP) of methyl methacrylate (MMA) in N,N-dimethylformamide (DMF) in the presence of the catalytic systems, namely, CCl4-FeCl3-1-acetyl-2-phenylhydrazine (APH) and CCl4-FeCl3-ascorbic acid (AA) is reported. The living feature of this process was confirmed by obtaining well-defined polymers with controlled molecular weight, narrow molecular weight distribution, and a chain-extension experiment. Both reducing agents, an APH as well as an AA, possess the equal kinetic activitis.

Item Type: Article
Subjects: East India Archive > Chemical Science
Depositing User: Unnamed user with email support@eastindiaarchive.com
Date Deposited: 23 Jun 2023 06:49
Last Modified: 23 Oct 2024 03:53
URI: http://ebooks.keeplibrary.com/id/eprint/1518

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